ISSN:
1434-1948
Keywords:
Arene complexes
;
Chromium
;
Cyclohexadienyl complexes
;
Dinuclear complexes
;
Manganese
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of secondary α-cyano or α-sulfonyl carbanions with cationic (η6-arene)tricarbonylmanganese complexes affords neutral mono- and dinuclear tricarbonyl(η5-cyclohexadienyl)manganese complexes. The X-ray analyses of three (η5-cyclohexadienyl)Mn complexes (two mononuclear and one dinuclear) obtained by addition of α-cyano carbanion to cationic (η6-arene)manganese complexes are reported. The addition of benzylic carbanions of (η6-arene)tricarbonylchromium complexes to cationic (η6-arene)manganese complexes gives rise to the formation of the corresponding heterodinuclear [(η5-cyclohexadienyl)manganese-(η6-arene)chromium] complexes.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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