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Cyclialkylation of Arylalkyl Epoxides with Solid Acid Catalysts (1999)

Elings, Jacob A. ; Downing, Roger S. ; Sheldon, Roger A.

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 837-846

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Details

ISSN: 1434-193X

Keywords: Friedel-Crafts reaction ; Hydroxyalkylation ; Aromatics ; Epoxides ; Zeolites ; Clays ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: -Solid acids, such as zeolites and clays, catalyse the intramolecular hydroxyalkylation (cyclialkylation) of several arylalkyl epoxides in moderate to excellent conversions and selectivities. The use of solid acids in these cyclialkylations provides a cleaner, better alternative to conventional Lewis and Brønsted acids, enabling a more facile workup of reaction mixtures and, in several cases, better selectivities.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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