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Digitale Medien

The Berry phase in molecular physics (1992)

Bohm, A. ; Kendrick, B. ; Loewe, Mark E.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 41 (1992), S. 53-75

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Details

ISSN: 0020-7608

Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The geometric phase of quantum mechanics is introduced, and its physical effects are then studied in the context of molecular physics. By performing the most general Born-Oppenheimer procedure, we show how gauge groups appear in the study of molecules. This method is then applied to the doubly degenerate Λ-levels of a diatomic molecule. The resulting dynamics for the slow angular motion of the dumbbell is equivalent to that of a Dirac monopole.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/qua.560410108

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