ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Exciton transfers in the two-dimensional and spin-canted antiferromagnet (C2H5NH3)2MnCl4 were studied by investigating the absorption spectra 6A1g → 4T2g(4D) of Mn2+. A magnon side band (exciton-magnon simultaneous excitation) which has an anomalous shape with the cutoffs at the low-energy as well as the high-energy sides was observed. This anomalous shape could be reproduced in calculation as magnon side band, considering both the intersublattice and intrasublattice exciton transfers. From the analysis of this band shape, the magnitudes of the intersublattice and intrasublattice exciton transfers are estimated to be 10.2 and 6.8 cm-1, respectively. In the case of simple antiferromagnets without spin canting, the intersublattice exciton transfer process is forbidden because of the spin angular momentum. However, in the case of (C2H5NH3)2MnCl4, the prohibition of the intersublattice exciton transfer is removed by the canted-spin arrangement.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560180236
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