ISSN:
0170-2041
Keywords:
Dithio Esters
;
Thiono Esters
;
Thioamides
;
Azodicarboxylates
;
Azodicarboxamides
;
Trithiomesoxalamides
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Dithio and Thiono Esters, 56. - Reaction of Thio Esters and Thio Amides with Azodicarboxylic Acid DerivativesDithio and thiono esters 1 react with azodicarboxylates 3 to form the addition products 4 or the oxidation products 5 in varying ratios. With malonates, malonamides and dithionomalonates only the addition products 7 were obtained. N,N,N′,N′-Tetramethyldithiomalonamide yields with azodicarboxylic acid derivatives 3 either the normal addition product 8, the β-elimination product 9 or N,N,N′,N′-tetramethyltrithiomesoxalamide (10A), the first stable vicinal trithiocarbonyl compound.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1992199201153
Permalink