ISSN:
1042-7147
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Bis(exocyclic)dienes were prepared by the reaction of 2,3-dibromomethyl-1,3-butadiene with aromatic diamines. The diamines were 4,4′-methylene dianiline, 4,4′-oxy dianiline, benzidine, and α, α′-bis(4-aminophenyl)-p-isopropyl benzene (EPON HPT 1061). Polymers were synthesized by the Diels-Alder reaction of these bisdienes with bis(4-maleimidylphenyl) methane. Flexible films were obtained for diene: dienophile ratios ranging from 0.7 : 1 to 0.8 : 1. Films were found to be insoluble in organic solvents and those cured above 120°C were insoluble in concentrated sulfuric acid. The polymers were characterized by IR, TGA, and elemental analysis.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pat.1990.220010201
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