ISSN:
1436-5073
Keywords:
molybdenum
;
spectrophotometry
;
solvent-extraction
;
sodium borohydride
;
thiocyanate
;
surfactants
;
soil
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A new, simple and specific spectrophotometric method for the determination of Mo in the soil extracts is described. Mo(VI) is reduced to Mo(V) with sodium borohydride and allowed to react with SCN− ions in the presence of cationic and neutral surfactants e.g. CPC and TX-100 in the acidic aqueous solution. The molar absorptivity of the complex in both the aqueous, and toluene solutions is (2.30) × 104 1mol−1 cm−1 at absorption maximum, 460 nm. The extraction-procedure preconcentrated Mo at least 3-folds. the detection limit is 125ng Mo/g soil. The analytical variables of the method have been optimised and composition of the complex is proposed. None of the tested foreign ion interfered in the determination of Mo up to a large amount. An attempt for the removal of Fe-interference in the determination of Mo in soil extract has been described. The method has been found to be satisfactorily applicable for the determination of Mo in hot water leachates and acid digested soil solutions at lower ppm levels.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01244750
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