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  • Polymer and Materials Science  (33)
  • Biochemistry and Biotechnology  (4)
  • fusion breeder  (3)
  • 1
    ISSN: 1572-9591
    Keywords: fusion breeder ; molten salt blanket ; molten salt processing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Several continuous salt processing options are available for use in molten salt fusion breeder blanket designs: fluorination only, fluorination plus reductive extraction, and fluorination, plus reductive extraction, plus metal transfer. The effects of processing on blanket performance have been assessed for these three levels of processing and various equilibrium uranium concentrations in the salt. A one-dimensional model of the blanket was used in the neutronics analysis, which incorporated transport calculations with time-dependent isotope generation and depletion calculations. The method of salt processing was found to have little affect on the level of radioactivity, toxicity, or the thermal behavior of the salt during operation of the reactor. The processing rates necessary to maintain the desired uranium concentrations in the suppressed-fission environment were quite low, which permitted only long-lived species to be removed from the salt. The effects of the processing therefore became apparent only after the radioactivity due to the short-lived species diminished. The effects of the additional processing (reductive extraction and metal transfer) could be seen after approximately 1 year of decay, but were not significant at times closer to shutdown. The reduced radioactivity and corresponding heat deposition were thus of no consequence in accident or maintenance situations. Net fissile production in the Be/MS blanket concept at a fusion power level of 3000 MW at 70% capacity ranged from 5100 kg/year to 5170 kg/year for uranium concentrations of 0.11% and 1.0%233U in thorium, respectively, with fluorination-only processing. The addition of processing by reductive extraction resulted in 5125 kg/year for the 0.11%233U case and 5225 kg/year for the 1.0%233U case.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of fusion energy 5 (1986), S. 317-326 
    ISSN: 1572-9591
    Keywords: magnetic fusion production reactor ; tritium production ; fusion breeder ; nuclear analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Tandem-mirror- and tokamak-based magnetic fusion production reactors are predicted to have tritium breeding ratios of 1.67 and 1.49, respectively. The latter value replaces one (1.56) that is used elsewhere in the sequence of papers in this issue. Blanket energy multiplication for both is predicted to be about 1.3. With the tandem mirror operating in the plutonium production mode, the net plutonium-plus-tritiurn breeding ratio is 1.74. Blanket energy multiplication for the plutonium mode is predicted to be 2.4 at a plutonium-uranium ratio of 0.7% and a uranium volume fraction of 3%.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of fusion energy 6 (1987), S. 59-64 
    ISSN: 1572-9591
    Keywords: magnetic fusion production reactor ; tritium production ; fusion breeder ; economic analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The magnetic fusion reactor for the production of nuclear weapon materials, based on a tandem mirror design, is estimated to have a capital cost of $1.5 billion and to produce 10 kg of tritium/year for $22,000/g or 940 kg/year of plutonium in the plutonium mode for $250/g plus heavy metal processing. A tokamak-based design is estimated to cost $1.5 billion and to produce 10 kg of tritium/year for $29 thousand/g. For comparison, a commercially sized tandern mirror fusion breeder selling excess electricity and fissile material to commercial markets is estimated to cost $3.6 billion and to produce tritium for $2.6 thousand/g and plutonium for $34/g plus heavy metal processing.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 184 (1983), S. 463-473 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Diaryliodonium salts undergo facile copper catalyzed reduction in the presence of Sn(II) compounds. Such redox couples can be employed for the in situ generation of active initiators for cationic vinyl and ring opening polymerizations. Two mechanisms are proposed for the reduction reaction to explain the stoichiometry of the reactants and nature of the products formed. The polymerizations of several representative cationically polymerizable monomers were studied.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 3293-3309 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: All aromatic polyimides bearing diarylsulfide linkages in the main chain were prepared either by condensation of a sulfur containing dianhydride with an aromatic diamine or the condensation of a sulfur containing aromatic diamine with a dianhydride. Phenylation with diphenyl iodonium salts was then used to convert the diarylsulfide groups to triarylsulfonium salts. The resulting photosensitive polyimides were shown to undergo main chain cleavage during photolysis using UV irradiation. These new polyimides are candidates for positive working, high temperature photoresist materials.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 479-503 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparation of a variety of silicon-containing epoxy monomers and oligomers is described and their reactivity in photoinitiated cationic polymerization examined. Monomers and oligomers having terminal cycloaliphatic epoxy groups were found to be especially reactive in cationic polymerization. These materials are attractive candidates for use in coatings, adhesives, and elastomers.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3951-3968 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes the synthesis and characterization of a series of (4-alkoxyphenyl)phenyliodonium salts which are excellent photo- and thermal-initiators for the cationic polymerization of vinyl and heterocyclic monomers. These compounds are easily prepared by straightforward synthetic techniques and display very good solubility and photoresponse characteristics which make them especially attractive for use in UV curing applications. Those compounds with alkoxy chains of eight carbons and longer are essentially nontoxic.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1197-1215 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This first paper on the topic of polydimethylsiloxane-vinyl block polymers describes the development of a unique class of vinyl functional silicon containing free-radical initiators which can be used in the synthesis of block polymers. Details of the synthesis and characterization of these initiators are described together with the kinetics of their thermolysis. Specific conditions are described under which these initiators can be condensed with α,ω-hydrogen functional polydimethylsiloxane oligomers by a platinum-catalyzed hydrosilylation reaction to yield macroinitiators.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The thermolysis of polydimethylsiloxanes containing thermally labile bis(silyl pinacolate) groups in the backbone in the presence of various vinyl monomers leads to the direct synthesis of block polymers. Depending on the monomer chosen, simple triblock or multisequence block polymers can be readily prepared. Analysis of the products of the block polymerizations using various styrenic-type monomers shows that only block polymers are obtained, i.e., no homo-polymers are formed. These block polymers display evidence of phase separation such as intense iridescence and solvent-dependent mechanical properties. The mechanical properties of these block polymers have been measured and found to be highly composition dependent. Depending on the block length and the relative portions of the hard (vinyl) and soft (polydimethylsiloxane) blocks, one can produce either thermoplastic elastomers or rubber-modified thermoplastics.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 25 (1983), S. 497-511 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model for glucose-to-ethanol fermentation at high yeast cell concentrations was developed. The feasibility of improving fermenter productivity over that of a conventional continuous-stirred-tank fermenter by using multiple stage reactors and yeast cell recycling was predicted by computer simulation. The optimum size distribution for multistage fermentors was obtained for different glucose feedstream concentrations and different glucose conversion levels. Productivity increases over a single-stage reactor ranged from 1.2-2.0 times. The use of yeast cell recycling to increase cell concentration and productivity increases of over 4.0 times that of a system without recycling.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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