ISSN:
0268-2605
Keywords:
organotin
;
2-thionaphthalene
;
synthesis
;
crystal structure
;
biological activity
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A series of di- and tri-organotin complexes of 2-thionaphthalene of general formula RR′R″SnL (R=R′=R″=C6H5, CH3, n-C4H9, C6H11, C6H5CH2; R=R′=C6H5CH2, R″=Cl; R=R′=Me, R″=C10H7S and L=2-thio-naphthalene, C10H7S) have been prepared by the reaction of di-or tri-organotin chloride(s) with 2-thionaphthalene. All compounds have been characterized by elemental analysis, IR, MS, NMR (1H, 13C, 119Sn) and 119Sn Mössbauer spectroscopies. X-ray crystal structures of the representative compounds (C6H5)3SnL and (CH3)2SnL2 confirm a tetrahydral geometry about tin. The biological activities of these compounds against various bacteria and fungi have been investigated. © 1997 by John Wiley & Sons, Ltd.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
Permalink