ISSN:
0947-3440
Keywords:
2-exo-Substituted brendene derivatives
;
2,5-Disubstituted brendene derivatives
;
Cyclopropylcarbinyl cation
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of 2-exo-substituted brendene derivatives 3a, 5a and 6 as well as 2,5-disubstituted brendene derivative 7 is described, starting from the readily available tetracyclo-[4.3.0.02,9.04,8]nonanone 1. The cationic rearrangement reactions of tetracyclic skeleton of 1 and 2 have been studied. The mechanism of these reactions is discussed. The preparation of inaccessible exo-alcohol 2a by reduction of ketone 1 is presented.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1995199510264
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