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  • Bromosulfenyl(trihalogeno)phosphonium salts  (1)
  • Trifluormethylchloroiodinenitrate  (1)
  • Vibrational Spectra  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Reaktion von Chlornitrat mit CF3I: Isolierung von Trifluormethylchloriodnitrat CF3I(Cl)ONO2 und Kristallstruktur von Trifluormethylioddinitrat CF3I(ONO2)2 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1552-1557 
    Details
    ISSN: 0044-2313
    Keywords: Chlorine Nitrate ; Trifluormethylchloroiodinenitrate ; Trifluormethyliodinedinitrate ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of Chlorine Nitrate with CF3I: Isolation of Trifluormethylchloroiodinenitrate CF3I(Cl)ONO2 and the Crystal Structure of Trifluormethyliodinedinitrate CF3I(ONO2)2CF3I reacts with ClONO2 to Iodine(III)-compounds. After an addition CF3I(Cl)ONO2 is isolated and characterized by vibrational spectra. With surplus ClONO2 it is formed CF3I(ONO2)2.CF3I(ONO2)2 crystallizes monoclinic in the space group P21/c with the cell parameters a = 1 024.3(6) pm, b = 873.5(6) pm, c = 873.4(6) pm and Z = 4.We measered following bonding distances: I—O: 207.3(3) and 220.8(2) pm, I—C: 221.1(4) pm and N—O: from 119.1(4) to 141.5(3) pm.Through an intermolecular I ··· O-contact the central iodine becomes a distorted plane geometry.
    Notes: CF3I reagiert mit ClONO2 in einer oxidativen Additionsreaktion zu Iod(III)-Verbindungen. Das Additionsprodukt CF3I(Cl)ONO2 wird isoliert und schwingungsspektroskopisch charaktersiert. Mit überschüssigem ClONO2 bildet sich CF3I(ONO2)2.CF3I(ONO2)2 kristallisiert monoklin in der Raumgruppe P21/c mit a = 1 024,3(6) pm, b = 873,5(6) pm, c = 873,4(6) pm und Z = 4.Es werden folgende Bindungslängen gemessen: I—O: 207,3(3) bzw. 220,8(2) pm, I—C: 221,2(4) pm und N—O: 119,1(4) bis 141,5(3) pm.Durch einen intermolekularen I ··· O-Kontakt erlangt das zentrale Iodatom eine verzerrt-planare Umgebung.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210920
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Bromsulfenyl(trihalogen)phosphonium-Salze Cl3-nBrnPSBr+AsF6- (n = 0 - 3) und Cl3PSBr+SbF6-  -  Oxidative Bromierung von Thiophosphorylhalogeniden (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 615 (1992), S. 114-116 
    Details
    ISSN: 0044-2313
    Keywords: Bromosulfenyl(trihalogeno)phosphonium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bromosulfenyl(trihalogeno)phosphonium Salts Cl3-nBrnPSBr+AsF6- (n = 0 - 3) and Cl3PSBr+SbF6-  -  Oxidative Bromination of ThiophosphorylhalidesThe bromosulfenyl(trihalogeno)phosphonium salts Cl3-nBrnPSBr+AsF6- (n = 0 - 3) and Cl3PSBr+SbF6- are prepared by oxidative bromination of the corresponding thiophosphorylhalides with Br2/MF5 (M = As, Sb) and characterized by vibrational and NMR spectroscopy.
    Notes: Die Bromsulfenyl(trihalogen)phosphonium Salze Cl3-nBrnPSBr+AsF6- (n = 0 - 3) und Cl3PSBr+SbF6- werden durch oxidative Bromierung der entsprechenden Thiophosphorylhalogenide mit Br2/MF5 (M = As, Sb) dargestellt und schwingungs- sowie NMR-spektroskopisch untersucht.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926150923
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  • 3
    Electronic Resource
    Electronic Resource
    Darstellung und Charakterisierung von Trimethylsilyliod(III)-nitrat (CH3)3SiI(ONO2)2 und Methyliod(III)-nitrat CH3I(ONO2)2 (1997)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 659-663 
    Details
    ISSN: 0044-2313
    Keywords: Iodine Nitrates ; Trimethylsilyliodine(III) nitral (CH3)3SiI(ONO2)2 ; Methyliodine(III) nitrate CH3I(ONO2)2 Chlorine Nitrate ; Vibrational Spectra ; NMR Spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Formation and Characterization of Trimethylsilyliodine(III) Nitrate (CH3)3SiI(ONO2)2 and Methyliodine(III) Nitrate CH3I(ONO2)2(CH3)3SiI and CH3I yield with excess ClONO2 in an oxidative addition the Trimethylsilyliodine(III) nitrate and Methyliodine(III) nitrate, respectively. The compounds are characterized by vibrational and NMR-Spectra.
    Notes: (CH3)3SiI und CH3I reagieren mit überschüssigem ClONO2 in einer oxidativen Additionsreaktion zu Trimethylsilyliod(III)-nitrat bzw. Methyliod(III)-nitrat. Die Charakterisierung erfolgte mittels Schwingungs- und NMR-Spektroskopie.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.199762301105
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    Paper (German National Licenses)
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