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  • CO hydrogenation  (1)
  • Chemical Engineering  (1)
  • catalyst selectivity  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 8 (1991), S. 15-21 
    ISSN: 1572-879X
    Keywords: CO hydrogenation ; zeolite Y ; rhodium carbonyl clusters ; catalyst selectivity ; catalyst stabilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Catalysts prepared by a condensation reaction of Rh(CO)2(acac) within the supercages of zeolite Y made basic by treatment with NaN3 are active for CO hydrogenation and selective for low-molecular-weight olefins and methanol. High partial pressures of CO (or CO + H2) stabilize the catalyst. The predominant species in the catalyst are suggested to be rhodium carbonyl clusters trapped in the zeolite cages.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 357-362 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid composition-total pressure and liquid composition-liquid density data for the carbon dioxide-ethane system were measured at -31.7°, -17.8°, -3.9°, and 10.0°C (-25°, 0°, 25°, and 50°F ± 0.02°F), from 0 to 80 mole % CO2 at 10°C and 0 to 100% CO2 for the other isotherms. The Benedict-Webb-Rubin equation of state with a modified A0 mixing rule was used to correlate the composition-pressure data, with deviations in predicted pressures of only 0.8% average and 2% maximum. Vapor-liquid equilibrium compositions and component K values y/x were then predicted for this minimum boiling azeotrope system from 10° down to -56.7°C (50° to -70°F).
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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