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  • Polymer and Materials Science  (60)
  • CT complexes  (1)
  • Gradientpolymers  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Polyethylene-polystyrene gradient polymers III. Mechanical and rheo-optical studies of relaxation processes (1987)
    Springer
    Colloid & polymer science 265 (1987), S. 490-497 
    Details
    ISSN: 1435-1536
    Keywords: Gradientpolymers ; low densitypolyethylene ; polystyrene contents ; intralamellarloss processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper the structure correlation of PE-PS gradient polymers, modified by styrene LDPE films with their mechanical and rheo-optical properties, is presented. The specific structural changes of both the investigated materials can be demonstrated by using dynamic mechanical deformation studies. The influence of the penetrant on LDPE crystalline and amorphous phase order is shown. Some interesting mechanical behaviour of the gradient polymers, depending on the polystyrene contents, is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01412502
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  • 2
    Electronic Resource
    Electronic Resource
    Effects of photoselection on the kinetics of colour decay in a photochromic spiropyran/poly(alkyl methacrylate) matrixDedicated to Professor G. Manecke on his 65th birthday (1982)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 183 (1982), S. 1257-1262 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Photochromic measurements are reported on the decay of the coloured form of 1′,3′,3′-trimethyl-6-nitro[2H-(1)-benzospiropyran-2,2′-indoline] dispersed in poly(methyl methacrylate) and poly(ethyl methacrylate) matrices. Polarized light was used to photoselect molecules in specific orientations, and the data are analysed in terms of a free volume distribution controlling the kinetic matrix effect. A time correlation function is obtained which characterizes both the rotation and the isomerization of the molecule.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1982.021830520
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  • 3
    Electronic Resource
    Electronic Resource
    Glass transition phenomenon in vinylidene chloride-acrylonitrile copolymers (1971)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 15 (1971), S. 2687-2697 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Investigations of glass transition phenomena were carried out on vinylidene chloride - acrylonitrile copolymers, purified commercial samples of known composition. With a view to analyzing this effect, the following physical parameters were investigated: specific volume Vs,25, Tg, and volume expansion coefficients αL, αg, and Δα. The experimental results were analyzed on the basis of semiempirical and theoretical equations describing transitions to the glassy state. It was found that Tg dependence on weight fraction C2 of acrylonitrile may be described by Wood's equation, with k = 5.88. Applying Gibb's and Kanig's theories as well as relations given by Hirai and Small, the energies associated with intermolecular interactions (A*AB, E0, Eh, CED), and intramolecular interactions (stiffness energy ε) were calculated for copolymers of different composition. The copolymer Tg was found, above all, to depend on the stiffness energy ε, which increases with increasing acrylonitrile content in the copolymer.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1971.070151109
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  • 4
    Electronic Resource
    Electronic Resource
    Studies on soluble fraction of glow-discharge polysilazane formed from hexamethylcyclotrisilazane (1977)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 2013-2019 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The soluble part of glow discharge polysilazane prepared from hexamethylcyclotrisilazane was studied. The composition of the soluble fraction was examined by gas chromatography and mass spectrometry. It was found that the fraction contained five main components, and two of them, identified by mass spectrometry, were octamethylcyclotetrasilazane and bicyclic silazane dimer. A reaction mechanism leading to dimer formation from hexamethylcyclotrisilazane in glow discharge was proposed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1977.070210801
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  • 5
    Electronic Resource
    Electronic Resource
    Thermal degradation of poly(2,6-dimethyl-1,4-phenylene oxide). I. The mechanism of degradation (1978)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 2891-2899 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An analysis of products obtained from thermal degradation of poly(2,6-dimethyl-1,4-phenylene oxide) is presented. The techniques used for identification of monomeric and dimeric degradation products were gas chromatography and mass spectrometry. On the basis of this analysis a mechanism of thermal breakdown is established. It consists of the Fries-type rearrangement of the polymer chain in the first degradation step and statistical scission of benzyl bonds. The proposed degradation scheme accounts for the retention of ether linkage in the afterdegradation residue.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1978.070221015
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  • 6
    Electronic Resource
    Electronic Resource
    Low-density polyethylene filled with chalk and liquid modifier (1981)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 4047-4058 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Based on the concept of introducing a liquid layer between the polymer and filler, a composition containing low-density polyethylene, chalk, and oligomer of ethylene oxide was proposed. Compositions containing up to 50% chalk modified with ethylene oxide exhibit typical thermoplastic behavior, i.e., neck formation and plastic deformation. They also show high-impact strength and other good properties. On the basis of mechanical data, the main action of the ethylene oxide oligomer in the system is to inhibit crack generation and propagation.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1981.070261207
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  • 7
    Electronic Resource
    Electronic Resource
    Plasma polymerization of phenyl isothiocyanate (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 715-726 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thin polymer films were obtained by plasma polymerization of phenyl isothiocyanate. Polymerizations were carried out in rf (13.56 MHz) glow discharge generated in an electrodeless flow system. It was found that this monomer produces uniform films with a wide range of thicknesses, from hundreds of nanometers to tens of micrometers. The deposition rate appeared to be dependent on the substrate distance from the monomer inlet. The chemical structure of plasma polymer was characterized by using elemental analysis, IR spectroscopy, gas chromatography, and mass spectrometry. Elemental analysis showed that the composition of polymer depends on the substrate position in the reactor. It was observed that sulphur content decreased with increasing the substrate distance from the monomer inlet, whereas nitrogen content appeared to increase. The IR data revealed significant decrease in  - NCS groups content in the polymer as compared with the monomer spectrum and indicated for the appearance of new absorption bands corresponding to the —CN and C—H aliphatic, groups. The results account for a strong fragmentation of monomer in plasma involved in decomposition of isothiocyanate group and phenyl ring. The soluble fraction of polymeric material was examined by gas chromatography and then the separated products were analyzed by mass spectrometry. The soluble fraction was found to be composed of numerous low molecular-weight compounds. Identification of their structure revealed the presence of residual monomer, thiophenol, cyanobenzene, diphenyl, diphenyl sulphide, diphenyl disulphide, phenyl thiocyanate, dicyanobenzene, phenatroline, and some other oligomeric products. Formation of these compounds proves high susceptibility of —NCS group in the monomer towards different fragmentation reactions. The surface free energy and electrical conductivity of polymer films were evaluated. The surface free energy value was very close to those estimated for plasma polymers deposited from other benzene derivatives. The low electrical conductivity manifested by the investigated polymeric material indicated for its dielectric character. The photoelectrical measurements revealed some photoconductivity effect in this material.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240415
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  • 8
    Electronic Resource
    Electronic Resource
    Oriented PP-PS composites obtained by polymerization of styrene inside oriented PP matrices. I. Dispersion of PS and the composites' orientation (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1405-1413 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dispersion of polystyrene (PS) and the molecular orientation of the polypropylene-polystyrene (PP-PS) composites acquired by the in situ polymerization of styrene in the oriented PP matrices were characterized by microscopic observations, birefringence measurements, and differential scanning calorimetry. It has been shown that applied processing of the “envelope” polymerization leads to obtaining oriented composites with large contents and the specific dispersion of PS. Some composites exhibit a substantial gradient of PS concentration and a gradient of molecular orientation, both strongly dependent on the initial structure of the oriented PP matrix. The modification of the PP structure taking place during processing does not disturb the orientation of the matrices deformed to the higher draw ratios. The structural changes of the oriented PP induced by processing are reflected in the shrinkage behavior and mechanical properties discussed in the second part of this paper. © 1993 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070490808
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  • 9
    Electronic Resource
    Electronic Resource
    Oriented PP-PS composites obtained by polymerization of styrene inside oriented PP matrices. II. Shrinkage behavior and mechanical properties (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 637-644 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal shrinkage and the mechanical properties of oriented polypropylene-polystyrene (PP-PS) composites obtained by in situ polymerization of styrene in the oriented PP matrices were examined by the analysis of shrinkage stress curves and dynamic mechanical data. It has been shown that by changing the structure of the oriented matrices it is possible to control the properties of the obtained oriented composites. Some composites reveal an increased stability of the obtained oriented composites. Some composites reveal an increased stability of the molecular network at higher temperatures and the modulus of the material obtained from the matrix drawn at 90°C to the natural draw ratio is significantly increased. It is also shown that the differences between the untreated matrices and the PP component of the respective composites observed in the relaxation of the shrinkage stresses correspond very well with the differences seen in the mechanical loss in the frequency range of about 0.02 Hz. Such behavior suggests that similar molecular motions are involved both in the relaxation of shrinkage stresses and in this part of the mechanical loss. © 1993 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070500408
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  • 10
    Electronic Resource
    Electronic Resource
    Conductive polymer thermoelements (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 52 (1994), S. 1005-1006 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070520719
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