ISSN:
0935-6304
Keywords:
Gas chromatography, GC
;
Capillary columns
;
Deactivation
;
High-temperature silylation
;
Disilazanes
;
Cyclosiloxanes
;
Polysiloxanes
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
This retrospective article describes the beginnings and the development of silylation methods with diverse silazanes and siloxanes at high temperatures, and stresses their role in producing modern capillary columns characterized by a high degree of thermostability and adsorptive and catalytic inertness. Particular emphasis is placed on the outstanding contributions to this field of Kurt Grob, whose persilylation techniques provided the basis for the expansion of high resolution capillary gas chromatography.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240110608
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