ISSN:
0009-2940
Keywords:
Coronene(1-), radical anion
;
Potassium compounds
;
Graphite model studies
;
Calculations, MNDO
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Crystallization of potassium(1+) and the radical ion coronene(1-) from a mixture of tetramethylethylenediamine (tmeda), tetrahydrofuran (THF), and diethyl ether yields a monomeric solvated ion pair 1 with potassium unsymmetrically π-coordinated to an external ring of the polyaromatic system according to an X-ray structure determination and in agreement with a MNDO theoretical investigation.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270712
Permalink