ISSN:
0009-2940
Keywords:
Carbenes
;
Organosilicon compounds
;
Organotin compounds
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Imidazole Derivatives, XIII. - Carbene Complexes of Silicon and TinHerrn Professor Peter Paetzold zum 60. Geburtstag gewidmet.Stable adducts of the composition L · SiCl4 (2), L · SiR2Cl2 (3,4), and L · SnR2Cl2 (6) are formed by the reaction of the imidazol-2-ylidenes L (1) with the corresponding silicon and tin halides. For L = SiCl4 (2b; L = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene) and L · SnPh2Cl2 (6c; L = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) the monomeric nature of the compounds containing pentacoordinated silicon and tin is established by X-ray structure analyses. The reaction of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene (1c) with SnCl2 leads to the formation of the monomeric stannylene complex L · SnCl2 (7c; L = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) whose molecular geometry indicates a week carbon-to-tin donor bond [Sn—C(1) 2.290(5) Å].
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19951280307
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