ISSN:
0009-2940
Keywords:
Transition metal complexes with 1-selenoglucose
;
Glucose as ligand
;
Selenoglucose
;
Carbohydrates
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Metal Complexes of Biologically Important Ligands, LVII. - 1-Selenoglucose as Ligand in Metal ComplexesReactions of the in situ-prepared anion of acetylated 1-selenoglucose with chloro complexes give the compounds R'3 PAuSeR (R'=Me, El, Ph), cis;-(Ph3P)2Pt(SeR)2 and (η5C5H5)2Ti(SeR)2 (SeR=2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranosato-Se). The complexes (η5-C5H5)(OC)2FeSeR and (OC)3M(μ-SeR)2M(CO)3 (M=Fe, Ru) are prepared by the reaction of the diselenide RSeSeR with the dinuclear compound [η5-C5H5Fe(CO)2]2 and M3(CO)12 (M=Fe, Ru), respectively.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240407
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