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Coordination Chemistry and Catalysis. Investigations on the Synthesis of Cyclooctatetraene by the Method of W. Reppe (1964)

Schrauzer, G. N. ; Glockner, P. ; Eichler, S.

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 3 (1964), S. 185-191

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ISSN: 0570-0833

Keywords: Coordination modes ; Catalysis ; Cyclooctatetraenes ; Reppe chemistry ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The relationship between the structure and the catalytic activity of nickel(II) complexes in the synthesis of cyclooctatetraene by the method of W. Reppe is discussed. The cyclotetramerization of acetylene takes place within labile Ni(II)-acetylene π-complexes. Inhibition tests have made it probable that four molecules of acetylene are grouped around the nickel ion in the transition state, in a configuration which favors the formation of the eight-membered ring.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.196401851

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