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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 28 (1989), S. 519-522 
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Reversed-phase chromatography ; Separation of metal acetylacetonates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Using reversed-phase high-performance liquid chromatography acetylacetonate complexes with trivalent metals such as Al(III), Co(III), Cr(III) and Fe(III) have been examined in columns containing RP-2, RP-8 and RP-18 bonded phases. The mobile phase consisted of acetonitrile/water or methanol/water mixtures with various compositions. As shown the order of elution of the acetylacetonates depends on the type of the column packing and on the nature and concentration of the organic modifier in the mobile phase.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 18 (1984), S. 704-706 
    ISSN: 1612-1112
    Keywords: Ce(III) complexes ; Cation-exchanger in Ce(III) form ; Ion-exchange chromatography ; Chlorophenols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The separation of chlorophenols on Dowex 50 WX 8 200/400 mesh resin in the H+ form and in the M3+ form has been investigated using a mixture of aqueous sulphuric acid and organic modifiers (e.g. acetonitrile or isopropanol) as the eluent. It was shown that formation of Ce3+ complexes with chlorophenols is a more specific interaction than physical adsorption or phase partition. Full separation of the compounds examined was achieved by elution from a column with the resin in the Ce3+ form.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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