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Effects of NO and solids on the oxidation of methane to formaldehyde (1994)

Irusta, S. ; Lombardo, E. A. ; Miró, E. E.

Springer

Catalysis letters 29 (1994), S. 339-348

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ISSN: 1572-879X

Keywords: formaldehyde ; gas-phase reactions ; methane partial oxidation ; oxide catalysts ; nitric oxide

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The selective oxidation of methane has been studied both in the presence and absence of solids (inert or catalysts) with and without NO added, at 1 bar of total pressure. NO enhances the yield to formaldehyde, while the solids favor its decomposition. These results, together with abundant literature data, show a maximum for formaldehyde yield of about 4.0%.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00807113

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Computerized catalytic kinetics: A useful extension of the method of Wei and Prater (1971)

Lombardo, E. A. ; Hall, W. Keith

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 17 (1971), S. 1229-1233

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: An extension of the method of Wei and Prater has been devised for determining the relative rate constants for an isothermal, first-order, reversible, three-component system, namely, the catalyzed isothermal isomerization of n-butenes. The new method reduces the required work to one experiment.

Additional Material: 5 Ill.