ISSN:
0272-8397
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
A one-dimensional devolatilization model is developed for autoclave processing of themroplastic polyimide, graphite-reinforced, composites. The model rests on the assumption that continous gas passages are formed during processing due to partical crystallization of the polymer in the course of polymerization. Both DSC and optica microscopy indicate that crystallinity develops in the Avimid-III polyimide resin during polymerization, which in turn facilitates formation of cracks. These cracks heal upon removal of volatiles and polymer melting. Model-Calculated temperature profiles in the laminate during polymerization, and the predicted removal rates of volatile species (water, ethanol, NMP) are compared to experimental miniautoclave data for the DuPont Avimid K-III/IM6 system. Good agreement is obtained when the volumetric mass transfer coefficient required by the model is assumed to vary proportionally to the inverse of the changing resin viscosity. The model allows the investigation of desired cure cycle parameters for different laminate thicknesses.
Additional Material:
15 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pc.750150304
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