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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1976-1982 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A 200-s PSA cycle involving both pressure equalization and product backfill steps has been experimentally studied on a four-bed system, where LINDE 5 A zeolites were used as the adsorbent to separate oxygen from air. This cycle is operated under a pressure ratio of 4.3. During the experiment, the pressure history and flow rates, as well as the concentration of the product stream have been continuously monitored. This is the first time detailed experimental data on a four-bed system are presented. Under favorable conditions, this system produces better than 90% oxygen at a recovery of 17%. For the low-pressure ratio, such a recovery could not have been achieved without the pressure equalization step and the reduced purge operation. Recovery and throughput, however, are not as high as one would expect from a linear local equilibrium model. The self-broadening effect of the purge wave has been identified as the major cause of underperformance.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1033-1040 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Necessary and sufficient conditions for the robust stability and performance of the Smith-predictor controller, modeled under a norm-bounded uncertainty, are given in a general formulation. In addition, a practical stability condition is obtained as a special corollary of the main results. These conditions provide useful and practical guidelines for the development of a systematic robust design method. In particular, an application is developed for the robust control of first-order deadtime systems with simultaneous uncertainties in all three parameters of the model. A simulation example and the results of a case study on the robust level control of a coupled-tanks apparatus are provided for illustration.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1793-1797 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2555-2562 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An enhanced automatic tuning procedure developed for process control of PI and PID controllers addresses several potential problems present in current standard autotuners. The proposed enhanced autotuner uses a novel technique based on relay feedback to estimate the process frequency response at two specified phase lags on the Nyquist curve automatically. An iterative procedure then uses these two points to obtain a transfer-function model of the process. Based on this model and a controller-selection scheme, an appropriate controller (PI or PID) is applied to the process automatically. The controller is tuned so that the Nyquist curve of the compensated system is appropriately shaped to satisfy a combined gain and phase-margin type of specification. The effectiveness of this enhanced autotuner is demonstrated both in simulations and in real-time experiments for level control of a coupled-tanks system.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 357-362 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid composition-total pressure and liquid composition-liquid density data for the carbon dioxide-ethane system were measured at -31.7°, -17.8°, -3.9°, and 10.0°C (-25°, 0°, 25°, and 50°F ± 0.02°F), from 0 to 80 mole % CO2 at 10°C and 0 to 100% CO2 for the other isotherms. The Benedict-Webb-Rubin equation of state with a modified A0 mixing rule was used to correlate the composition-pressure data, with deviations in predicted pressures of only 0.8% average and 2% maximum. Vapor-liquid equilibrium compositions and component K values y/x were then predicted for this minimum boiling azeotrope system from 10° down to -56.7°C (50° to -70°F).
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 517-519 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 147-152 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient diffusion of n-butane, iso-butane, and 1-butene in synthetic CaX(Na) spherical pellets is studied in a constant volume, well-stirred system. The intracrystalline diffusion coefficients are in the order of 10-14 cm2/s, and the activation energy is about 7.0 Kcal/g-mole. Experimental data agree well with a mathematical model developed to describe transient diffusion.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 1104-1110 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new model of enthalpy recovery is presented which is based on a microscopic-relaxation theory. The microscopic basis and manner of construction of the enthalpy-recovery model are discussed in detail. The qualitative features of the model are illustrated using numerical simulations. In particular, the way in which the effects of physical aging are produced is discussed. The qualitative features observed in differential-scanning-calorimetry experiments are reproduced, and a program of extensive simulations is proposed and outlined. The present microscopically based model is also used to suggest interpretations and possible modifications of currently used phenomenological enthalpy recovery models.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 16 (1995), S. 481-488 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The degree of crystallinity in polymers is commonly known to significantly affect their mechanical properties. To that extent, it also affects the mechanical properties - such as compression, buckling, and creep - of thermoplastic composites that are matrix dominant. For this reason, it is important that the degree of crystallinity in a thermoplastic composite be precisely determined, which is the focus of this paper. In particular, the crystallinity for a thermoplastic poly(phenylene sulfide) composite reinforced with glass fibers is determined using an X-ray diffraction technique (XRD). While conventional methods have been adopted for homogeneous phases, a modified method has been adopted to account for the heterogeneous nature of the composite. The results have also been compared with results obtained using DSC and DMA techniques, indicating that the XRD method yielded lower values, which are considered to be more accurate. This was attributed to the absence of a recrystallization effect in the XRD method, which was unavoidable in the other two methods.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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