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Digitale Medien

Kinetics of tetrachloroethylene photochlorination (1984)

Ledakowicz, S. ; Nowicki, L. ; Perkowski, J.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 345-352

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Photochlorination of tetrachloroethylene has been studied in a homogeneous liquid system. Kinetic parameters such as reaction orders for chlorine, tetracholoroethylene and light intensity, preexponential factor, and activation energy were evaluated from experimental data. The following kinetic equation was obtained by parameter estimation following the Marquardt procedure: \documentclass{article}\pagestyle{empty}\begin{document}$$ r = \left( {4.02 \pm 0.46} \right)10^{ - 5} \exp \left( { - \frac{{54,700 \pm 200}}{{RT}}} \right)I^{0.489 \pm 0.003} C_{Cl_2 }^{0.889 \pm 0.160} C_{C_2 Cl_4 }^{1.040 \pm 0.042} $$\end{document}

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550160405

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