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Kinetic study on oxygenation of Lingula unguis hemerythrin using the stopped-flow 02-jump method (1990)

Tachi'iri, Y. ; Ichimura, K. ; Yamamura, T. ; [weitere]

Springer

European biophysics journal 18 (1990), S. 9-16

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ISSN: 1432-1017

Schlagwort(e): Hemerythrin ; Oxygenation ; Lingula unguis ; Stopped-flow

Quelle: Springer Online Journal Archives 1860-2000

Thema: Biologie , Physik

Notizen: Abstract O2-jump experiments with an improved stopped-flow apparatus have been used to study oxygenation and deoxygenation processes in Lingula unguis hemerythrin. With an O2 electrode set in the observation cell, O2 concentration conld be obtained directly. The reliability of this method has been compared with other conventional methods. O2-jump (up and down) experiments were carried out with L. unguis hemerythrin at pH 6.8 (non-cooperative pH) and at pH 7.6 (cooperative pH). At pH 6.8, both O2-jump (up) and O2-jump (down) experiments showed single exponential processes which were consistent with the following scheme: $${\text{Hr + O}}_{\text{2}} \mathop \rightleftharpoons \limits_{{\text{k}}_{{\text{off}}} }^{{\text{k}}_{{\text{on}}} } {\text{HrO}}_{\text{2}} $$ . The value of k on was estimated to be (4.4 ± 0.5) × 105 M−1 s −1, and k off was (15 ± 5) s−1. These values are consistent with those obtained by the temperature-jump method (Zimmer et al. 1986). At pH 7.6, O2-jump (up) experiments showed two relaxation processes, whereas O2-jump (down) experiments showed a single exponential process. The faster process in the O2-jump (up) experiments could be attributed to the same process as that seen in the temperature-jump experiments (Zimmer et al. 1986). The slower process in the O2-jump (up) experiments corresponds to the process obtained in the O2-jump (down) experiments. The results are discussed in terms of a state with intermediate affinity in O2-binding and with the possible existence of a slow step in O2-binding.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00185415

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Digitale Medien

Water-Soluble contrast enhancing materials - new photobleachable dyes (1989)

Yonezawa, T. ; Kikuchi, H. ; Hayashi, K. ; [weitere]

Stamford, Conn. [u.a.] : Wiley-Blackwell

Polymer Engineering and Science 29 (1989), S. 898-901

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ISSN: 0032-3888

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Many styrylpyridinium compounds (SPC), which are very stable in the dark, were prepared and evaluated as photobleachable dyes for contrast enhanced lithography (CEL). The photobleaching characteristics of water-soluble contrast enhancing materials composed of SPC and water-soluble polymer depend on the structure of the SPC and the kind of polymers used. The technique using SPC-based CEL proved to be very effective for the resist pattern profiles.

Zusätzliches Material: 7 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pen.760291403

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Digitale Medien

Photosensitive resins containing p-dimethylaminobenzylidene derivatives and diphenyliodonium salt as photoinitiators (1987)

Ichimura, K. ; Kameyama, A. ; Hayashi, K.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 34 (1987), S. 2747-2756

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ISSN: 0021-8995

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: A series of p-dimethylaminobenzylidene derivatives was able to sensitize the photodecomposition of diphenyliodonium salt to afford highly photosensitive negative-type resins. When a polymer-bearing methacryloylated group in the side chain was sensitized with a combination of the p-dimethylaminobenzylidene compounds and the iodonium salt, the polymer demonstrated high sensitivity even to 488 nm light emitted from an Argon laser. The same photoinitiator systems were applicable to insolubilize poly(glycidyl methacrylate) through cationic photopolymerization. The storage stability of these types of photoinitiators depends on the structure of the benzylidene compounds; decreasing the basicity of the amino group enhanced the thermal stability.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/app.1987.070340810

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