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Critical behavior of nonionic micellar solutions (1989)

Hamano, K. ; Kaneko, T. ; Fukuhara, K. ; [et al.]

Springer

International journal of thermophysics 10 (1989), S. 389-396

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ISSN: 1572-9567

Keywords: critical phenomena ; coexistence curve ; light scattering ; diffusion ; micelles ; viscosity

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The critical behavior of micellar solutions of triethylene glycol monon-hexylether in water has been investigated in view of the issue of critical-point universality for such systems close to their critical mixing point. The values of the critical exponents obtained in this work are in excellent agreement with the theoretical ones for three-dimensional Ising-like systems. The dynamical critical behavior is also discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01133535

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Light scattering study of the swelling process of poly(acrylonitrile-co-butene)-graft-poly(acrylonitrile-co-methylacrylate) film (1994)

Goto, A. ; Kuwahara, N. ; Sato, H. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Polymer International 35 (1994), S. 219-224

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ISSN: 0959-8103

Keywords: copolymer ; film ; light scattering ; swelling ; Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The time evolution of the size and density of the swollen domains during the swelling of poly(acrylonitrile-co-butene)-graft-poly(acrylonitrile-co-methylacrylate) film in methanol was studied by light scattering measurements. The observed scattered light intensity was analyzed by the Guinier plot. The time evolution of the mean radius R(t) and number density N(t) of the swollen domains was given by R(t)3 ∼ t0.12 and N(t) ∼ t1.42.

Additional Material: 7 Ill.