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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 77 (1994), S. 945-947 
    ISSN: 1572-9613
    Keywords: Diffusion ; traps ; stretched exponential ; relaxation ; Kohlrausch ; electronic ; structural
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We construct a bridge between the standard diffusion-to-traps mathematical model of stretched exponential relaxation and the modern experimental database on both electronic and structural relaxation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 668-677 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanical behavior of various classes of inked and non-inked (dry) open-cell foam rollers has been investigated from stress/strain measurements in compression. Hysteresis, creep, and recovery in dynamic loading were used to differentiate the rollers as to their utility in printing applications. Creep, ∊c(t), and recovery, ∊r(t), were determined in a compression mode from force measurements and strain decay, ∊(t), i.e., Δ∊c(t) = ∊0 - ∊(t) [∊0 = ∊(t = 0)] or ∊c(t) = 2∊0 - ∊(t). The creep function, Δ∊c(t), represents the plastic strain, ∊pl(t = th), and is uniquely defined from the recovery function, Δ∊c(t) = ∊r(t = th), where th is the hold or contact time. The recovery results for a polyurethane ester (PUE) and acrylonitrile/butadiene (AB) rollers (dry/ink), poly(vinylidene fluoride) film (PVF2) (air/vapor) and low-density polyethylene film (LDPE) (air/vapor) were found to fit a master curve of the form Fr(θ) = EXP[-Kr(th)θ] = [∊r(t) - ∊∞(th)]/[∊0(t = O) - ∊∞(th)] at a reduced time of Kr(th)θ {θ = t/th and Kr(th) = k′r(th)th = C0/(th)α-1 (where C0 depends on the material's “dry” or “wet” state, α is a function of the type of material, and ∊∞ is the permanent set). These empirical results are consistent with the observed decreases in print intensity during transfer to a paper substrate and weight changes of the roller, i.e., creep and recovery are important in the printing characteristics of a given roller material. Other factors of importance in the overall transfer and print quality, but of longer-term considerations, are diffusion processes within the polymer and the nature of the polymer (e.g., porosity, chemical constitution, surface and interfacial tensions).
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 527-536 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Static measurements have been used to predict the dynamic response of ldquo;unboundedrdquo; open-cell noninked (dry) and inked foam materials. Creep, ec(t), and recovery, er(t), were determined in compression from static and dynamic modes. Force measurements, f(t), and strain decay, e(t), were used to determine the change in creep, δec(t). The change in creep represents the plastic strain, ep1(t=th), and is uniquely defined by the recovery function, er(t=th), where th is the hold time. Creep and recovery results of various classes of foam materials and nonfoam materials were found to fit a master curve of the form Fr(t) =exp[-k′r(th)t] = [er(t) - e00( th)]/[e0 (t = 0) - e00(th)] at a reduced time of k′r(th) t [k′r(th)] C0/(th)a (where Co depends on the material's “dry” or “wet” state), a is a function of the type of material, and em is the permanent set]. These empirical results are applicable to printing ink transfer and print quality. Other important factors of concern are diffusion processes within the polymer matrix and the nature of the polymer (e. g., chemical constitution, porosity, molecular weight, and solubility). © 1995 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 73-78 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The liquid heat capacities and heats of vaporization of three linear esters of poly(hexamethylene sebacate) with hexylcapped end groups (M(mol. wt.) = 370, 655, and 939) have been determined. The heats of vaporization of the oligomers measured at a mean temperature were corrected to 323.15 to 523.15°K by use of the experimental liquid (melt) heat capacities and the calculated gas heat capacities. The corrected heats of vaporization were fitted to the equation ΔHv = S(T)Mα + I(T), where the temperature dependence of the slope and intercept are represented, respectively, as S(T) = ClnT + Ko and I(T) = a T + bo, and α is an exponent. The results indicate (at corresponding molecular weights and constant temperature) that the ratio of the liquid heat capacities of the oligomer ester and the n-alkane, and similarly the ratio of the heats of vaporization, depend on the number of carboxyl groups in the oligomer ester chain.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 734-742 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: At a fixed vapor pressure p of the penetrant and constant temperature of the experiment, the sorption S = c/p or concentration c of the ethylacetate vapor in the uniaxially strained low density polyethylene (LDPE) increases most rapidly at low strains. If, however, on the basis of strain relaxation one separates the total strain ∊ into an elastic ∊e, and a plastic ∊pl, deformation, one obtains an almost linear increase of the concentration c or sorption S of the sorbate with elastic strain ∊e. The separation of ∊ = ∊e + ∊pl depends very much on the time th the sample is kept elongated and the vapor pressure p of the sorbate. The elastic component decreases and the complementary plastic fraction increases with th and p. An almost stationary state is reached after th of about 1/2 h. The calculation of the diffusion coefficient Ds1 from the first sorption immediately after the stretching is affected by this slow adjustment in the interval 0 ≤ th ≤ ½h and shows a pseudo maximum at a strain of ∊∼ = 10 percent. The first desorption experiment and all the later sorptions and desorptions yield the same DD = DS 〈 DS1 that is the correctly calculated diffusion coefficient D. The coefficient D decreases with the strain ∊ or ∊e in contrast with the expected increase of Da of the amorphous component. Such an increase of Da is expected as a consequence of the fractional free volume (FFV) increase caused by the elongation. According to the FFV concept, a decrease of the measured apparent diffusion coefficient D = ψDa requires that with increasing ∊, the tortuosity factor ψ decreases faster than the increase in Da.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 881-895 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Low-speed tack measurements (≈ 0.1-6.0 rad/s or ≈ 1-57 RPM) have been determined for polymeric-based solution inks and oil-based dispersion inks, tripropylene glycol (TPG), Igepal (I-530), and N-350 (viscosity calibration standard) fluids using a metal roller/incline method. The inks and fluids were tested under “unaged” or reference conditions at 25°C. The inks were “aged” at 70°C and, subsequently, tack measurements were made at 25°C. The tack (Ti) and angular speed (Wi) for the inks were empirically fitted as functions of incline angle (α) and “aged” time, tcd. A correlation was also made for tack and percent weight change, ΔWi. Other factors, such as viscosity, surface tension, humidity, and “aging” temperature, Tcd, were also found to affect the magnitude and variation of tack. Additionally, the results suggest that low-speed tack measurements are quite useful for selecting solution inks containing polymeric substances that possess the desirable spreading, mixing, and pressing properties in high-speed/high-volume printing and the component compatibility necessary for long-term performance. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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