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  • Chemistry  (2)
  • isotopic substitution  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 13 (1998), S. 391-396 
    ISSN: 1573-4846
    Keywords: silsesquioxanes ; MAS-NMR ; infrared ; isotopic substitution ; inorganic-organic copolymers ; cyclopentadienylrhodium dicarbonyl
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Copolymerization of cubane octavinylsilsesquioxane, {Si8O12}(CH=CH2)8, with the cubane silses-quioxane hydrides, {Si8O12}H8 and {Si8O12}(OSiMe2H)8 in the presence of C5H5Rh(CO)2 affords hybrid inorganic-organic copolymers incorporating monocarbonyl {C5H5Rh(CO)} species. These are of two types, one containing Rh(III) and the other Rh(I). The Rh(III) species appears to be that formed initially, and can be converted into the Rh(I) species by photolysis. BET measurements show that a significant increase in surface area occurs when the copolymerization is carried out in the presence of the rhodium complex.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 510-512 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 232-238 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dissolution and crystal growth on the (010) cleavage surface of mineral gypsum have been studied by scanning force microscopy, which allows observation of surfaces while they are in contact with aqueous solutions. Etch pits formed on the (010) surface in contact with solutions undersaturated with respect to gypsum are oriented in relation to the [001] zone axis. Edges parallel to [001] are stable or move only slowly. Edges parallel to [100] and [101] move more rapidly. Crystal growth by migration of step edges is observed in contact with supersaturated solutions. The inhibition of crystal growth by phosphonate produces gross changes in the texture of steps and terraces.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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