ISSN:
1588-2837
Keywords:
WGSR
;
pyridine
;
rhodium complexes
;
poly(4-vinylpyridine)
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Catalysts for the water gas shift reaction prepared from Rh(COD)(amine)2 PF6 (COD=1,5-cyclooctadiene, amine=4-picoline, 3-picoline, 2-picoline, pyridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with 80% aqueoux 2-ethoxyethanol for 1×10−4 mol Rh/0.5 g of polymer, P(CO)=0.9 atm at 100 °C, are described. The role of the coordinated amine effect on the catalytic activity was investigated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02475779
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