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  • 1
    ISSN: 1573-0417
    Keywords: sediment facies ; sediment geochemistry ; sedimentation ; cores ; tephra stratigraphy ; hydrothermal activity ; paleolimnology ; New Zealand
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Lake Rotoiti in Taupo Volcanic Zone was formed by damming of the drainage system through the floor of Okataina Caldera. Basin sediments are predominantly silt or sand, with mineralogy consistent with derivation from local silicic rocks and airfall tephras. Sandy lithofacies around the shoreline are wave worked deposits. Sand and gravel lithofacies in deeper water and on steep slopes are largely relict or airfall tephras, or both. Profundal sediments are diatomaceous silts. Organic-rich diatomaceous silts also accumulate in near-shore wave-damped zones under weed beds. Short cores penetrated the Tarawera (1886 AD) and Kaharoa (1180 AD) Tephras, identified by their stratigraphic position, geochemistry and mineralogy. Localised slumping is evidenced from secondary tephras interbedded and redeposited within the basin silts. Sedimentation rates in the basins, estimated from the age of bounding tephras, are 0.9 to 4.0 mm y-1, and are highest under the influence of inflowing water from adjacent Lake Rotorua. For several hundred years prior to the Tarawera eruption sediment accumulation rates and the sediment geochemistry remained unchanged; deposition was predominantly biogenic opaline silica with a small terrestrial component. The Tarawera eruption deposited a terrestrial-silica, aluminum-rich primary tephra across the lake, which was followed by reworked tephra from within the catchment, the effects of which were progressively diluted by biogenic opaline silica as conditions stabilised. While the major effects of the eruption have been rapidly absorbed the lake has not returned to pre-eruption background conditions. A new equilibrium has been attained in which Tarawera Tephra continues to be eroded into the lake and is the principal source for a doubling of sedimentation rates following the eruption. High arsenic levels in some diatomaceous silts are attributed to episodic venting of hydrothermal fluids or gases into the water column.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 558-563 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Development of an Automated Trace-Matrix Separation Technique for the Determination of Trace Metals in Pure Titanium and TitaniumdioxideThe determination of metal traces in pure titanium with ICP-AES or ICP-MS requires an effective trace-matrix separation technique to eliminate interferences. After digestion in HF and HNO3 the traces can be separated from the matrix using a cation exchanger column. A computer controlled pumping system is used for the automatic control of the procedure of preconcentration, elution and determination. The method requires a minimum of chemical manipulation and reduces the risk of contamination by using only subboiled acids. Recovery rates of more than 90% and high precision are obtained for 16 analytes. For most of the elements detection limits in the range of 1 to 10 ng/g titanium can be achieved.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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