ZIB

1

Digitale Medien

The viscosity of liquid mixtures (1960)

McAllister, R. A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 6 (1960), S. 427-431

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ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The theory of viscosity of liquid mixtures presented here is based on Eyring's theory of absolute reaction rates. The most important conclusions drawn are that for liquids the free energies of activation for viscosity are additive on a number fraction or mole fraction basis and that interactions of like and unlike molecules must be considered. Methanol-toluene, benzene-toluene, and cyclohexane-heptane systems were analyzed with a three-body model and found to fit within the accuracy of the experimental data. Acetone-water mixtures fit a four-body interaction much better. Indications are that to describe acetone-water mixtures well would require consideration of seven- or eight-body interactions.

Zusätzliches Material: 8 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690060316

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2

Digitale Medien

Densities of liquid-acetone-water solutions up to their normal boiling points (1957)

Thomas, K. T. ; McAllister, R. A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 3 (1957), S. 161-164

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ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The densities of acetone-water liquid solutions have been measured over the entire composition range from 20°C. to within 3° to 7°C. of the normal boiling point of the mixture. The density was measured with a Robertson pycnometer (13), which was modified slightly. The density values are thought to be accurate to within ±0.00005 density units. The technique for determining density values of the volatile mixture near the boiling temperature is given in some detail. The refractive index (nD25) of pure acetone has been redetermined and equals 1.35596 ± 0.00003.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690030206

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3

Digitale Medien

Surface tension of acetone-water solutions up to their normal boiling points (1957)

Howard, Katherine S. ; McAllister, R. A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 3 (1957), S. 325-329

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ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The surface tensions against air of acetone-water solutions have been measured over the entire composition range from 20°C. to generally within 1° to 10°C. of the normal boiling points. The capillary-height method was employed and the results are thought to be accurate to better than ±0.5%.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690030308

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4

Digitale Medien

Pulsations in sieve-tray and bubble-cap distillation towers (1958)

McAllister, R. A. ; Plank, C. A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 4 (1958), S. 282-284

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ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: A periodic pulsation of the frothing mass of liquid and vapor on a sieve tray and a bubblecap tray is reported. An equation is proposed which relates the frequency of the oscillation to the velocity of sound, the physical dimensions of the systems, and the flow rates of the gas and liquid. The equation is a modification of the acoustical analogy to the classical Helmholtz resonance in electrical circuits having both capacitance and inductance. The oscillation is shown to decrease back-mixing on the tray, and thus to result in an increase in the Murphree vapor efficiency.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690040309

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5

Digitale Medien

The viscosity of acetone-water solutions up to their normal boiling points (1958)

Howard, Katherine S. ; McAllister, R. A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 4 (1958), S. 362-366

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Details

ISSN: 0001-1541

Schlagwort(e): Chemistry ; Chemical Engineering

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung

Notizen: The viscosity of acetone-water liquid solutions has been measured over the entire concentration range at temperatures from 20°C. to generally within 1° to 10°C. of the normal boiling point. A capillary suspended-level viscometer was used, and the authors estimate that the results are accurate to ±0.2%. Both kinematic and absolute viscosities are given, and the results have been extrapolated to the boiling point of the solutions. The calibration of the Cannon-Ubbelohde viscometer is discussed in detail.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/aic.690040326

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