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  • Chemistry  (20)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 414-418 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The optimal unsteady control of a jacketed tubular reactor with and without heat generation due to chemical reaction in response to a step disturbance in the feed stream concentration is computed. More rigorous control action was found to be necessary for the case with heat generation than without heat generation. Convergence of the method was also investigated with fixed and free final time.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 233-240 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that existing methods for design of optimal regulators by the Wiener-Hopf procedure must be modified in order to be applicable to unstable and/or nonminimum phase plant or disturbance transfer functions, such as are frequently encountered in the chemical industry. Solutions are developed for three cases: I. stable, but possibly nonminimum phase, plant and disturbance transfer functions; II. minimum phase, but possibly unstable, plant with no restrictions on the disturbance transfer functions; and III. prestabilized, with a proper modification to retain the original control effort inequality constraints, but possibly nonminimum phase plant and disturbance transfer functions. Case III gives the general solution for regulation of linear, time-invariant, lumped-parameter systems. When prestabilization is not necessary, it reduces to case I. Where applicable, solutions by the method of case II frequently involve less algebra than in case III.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 240-248 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Wiener-Hopf procedure for synthesis of optimum constrained linear feedback regulators has been extended in part I to all linear time-invariant lumped parameter systems. The solution is here applied to the control of the output concentration of an exothermic, stirred tank reactor operating close to an unstable steady state, by constrained manipulation of a cooling water flow rate, in the presence of a randomly fluctuating inlet concentration.When the spectral density of disturbance is given (for example, white noise through a first-order time delay, or a series of randomly alternating steps), the optimum controller has three modes: proportional, derivative, and integral with minor feedback. The responses of the nonlinear reactor and the linearized reactor control systems to a series of alternating deterministic step inputs and Gaussian distributed inputs are simulated, and a sensitivity study of the linearized system with respect to variations in process, controller, and disturbance parameters is made in order to demonstrate the feasibility of the method.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 410-414 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The necessary conditions for optimization of a system governed by a nonlinear vector first-order partial differential equation with two (space and time) independent variables, such as governs the unsteady behavior of tubular flow reactors, are derived. Rather general objective functionals and boundary conditions, such as the recycle of unconverted reactant with an appropriate time delay for separation and a free choice of final time, are allowed. A gradient technique in control space is formulated, and it is shown that distinct computational advantages can accrue from the use of the method of characteristics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 672-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 776-792 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 59-64 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental equipment to study the film boiling of liquid nitrogen on a porous heat source with vapor suction was developed. The electrically heated element was a 3.69 in. sintered stainless steel screen, which was also used as a resistance thermometer in conjunction with an a.c. potentiometric circuit. In preliminary work, this mode of heat transfer was unstable, but stability was achieved by placing a porous flow control element on the liquid side of the heater. It was found that the Nusselt number was a function of only the Reynolds number; the heat transfer coefficient was increased by a factor of as much as 2.5 over the heat transfer coefficient in normal film boiling; it was possible to vary independently any two of the three variables, heat flux, flow rate through the plate, and temperature difference; and the generated vapor was considerably superheated. Fluctuations in the local surface temperature were measured in film boiling from both porous and nonporous flat plates, indicating that momentary solid-liquid contacts can occur, for all practical purposes, in film boiling.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 361-369 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A free-radical polymerization with kinetic equations taking into account monomer, polymer, and solvent transfer and initiation, termination, propagation, and inhibition reactions was studied both experimentally and by simulation to determine the performance of various Kalman filters, with feasible measurements used.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 24-26 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Conditions for the incomplete displacement of gas from the valley between two parallel ridges by a liquid-drop front advancing over the ridges are calculated. The significant parameters are found to be the liquid density, surface tension, contact angle, and geometry of the ridges. The solution may be obtained analytically or, more conveniently, graphically. Surface roughnesses are divided into four classes, one of which can stably switch from liquid - to gas - fill, and another vice versa. This may account for some of the hysteresis effects reported in bubble nucleation. It is pointed out that surfaces consisting predominately of cavities are more likely to follow these considerations than grooved surfaces, owing to displacement of gas by advance of liquid along the grooves. An example important in boiling and cavitation theory is worked out, and qualitative agreement with the literature is shown.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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