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Mono(cyclooctatetraenyl)samarium Complexes: the Return of the Normally “Inaccessible” Bis(trimethylsilyl)amido Derivative (1999)

Visseaux, M. ; Dormond, A. ; Barbier-Baudry, D.

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1827-1830

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ISSN: 1434-1948

Keywords: Samarium ; Early organolanthanides ; Bis(trimethylsilyl)amido ; Cyclooctatetraenyl ; Lanthanides ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The complexes [(COT)Ln{N(SiMe3)2}(THF)] (Ln = late lanthanide metal) are readily accessible but, until now, the samarium analogue has proved elusive. The latter can be formed in solution but is easily desolvated during the isolation process, leading to a highly associated complex which is only soluble in coordinating solvents or in the presence of ancillary ligands.

Type of Medium: Electronic Resource

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