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  • Chemistry  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1282-1289 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The pressure loss between the mold and the nozzle in the injection molding of bar and box moldings has been monitored. The pressure drop observed during filling of the mold is reduced during the packing stage but remains finite. This has been attributed in the literature to solidification of polymer across the cavity transducer and to melt relaxation phenomena. Experiments have been carried out with hot molds to prolong the packing stage at the expense of the ‘cooling’ stage. Under these circumstances the pressure drop is reduced but not eliminated. The observed pressure drop may be related to the viscosity of the melt and its dependence on pressure and temperature although strain-induced crystallization and the pressure dependence of the melting point can confer effects similar to the cooling stage.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 616-620 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Detailed studies have been carried out on the anisotropy of creep and creep rupture behavior of thermoplastics oriented by the imposition of a large permanent deformation. This deformation is usually such as to produce simple fiber symmetry within the specimen. Experimental techniques have been devised for the accurate measurement of all three principal strains during tensile creep on small samples which are cut from the oriented specimens at various angles to the symmetry axis. In this way a full characterization of the creep behavior up to strains of 5 percent has been obtained at room temperature.Results are presented for work on rigid poly (vinyl chloride), poly(methyl methacrylate), and low density polyethylene. The results are discussed in terms of the time dependence and nonlinearity of the anisotropy. Creep rupture results on similar specimens are also presented and discussed. Anisotropy due to orientation is shown to be important in determining engineering properties and in understanding structure-properties relationships.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 8 (1987), S. 16-21 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes an investigation into the fiber orientation in a number of center sprue fed cavities in short glass fiber filled polypropylene and nylon. The data have been interpreted in terms of a generalized five-layer structure resulting from the frozen skin formation and the high and low shear levels in the flowing melt. The implications for scaling up the mold size are discussed from the results obtained with different shot volumes. The fiber structure was observed to depend on location in the molding, local injection time, and injection rate. In addition the occurrence of fiber-free layers within the moldings using the filled polypropylene increases with an increase in shot volume, which produces an inherent ‘scale-up’ problem. Notwithstanding the mold geometry subtleties, the fiber orientation in all the moldings follows similar patterns and trends.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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