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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 2 (1988), S. 297-302 
    ISSN: 0268-2605
    Keywords: Arsenobetaine ; dimethyl(ribosyl)-arsine oxides ; dimethyl(2-hydroxyethyl)arsine oxide ; arsenate ; trimethylarsine oxide ; arsenic metabolism ; marine animals ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Trimethyl(carboxymethyl)arsonium zwitterion (arsenobetaine) is virtually ubiquitous in marine animals consumed by man. Experimental work on the transformation of arsenate to arsenobetaine in the marine environment is reviewed. Current evidence favors the conversion of arsenate to dimethyl(ribosyl)arsine oxides by algae, and the microbially mediated transformation of dimethyl(ribosyl)arsine oxides to arsenobetaine or to its immediate precursors in the sediments. Information about the transfer of arsenobetaine from the sediments to marine animals is lacking.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 11 (1997), S. 281-287 
    ISSN: 0268-2605
    Keywords: arsenic ; marine animals ; analysis ; HPLC-ICP MS ; algae ; arsenobetaine ; trimethylarsine oxide ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The chemical forms of arsenic in some herbivorous or mainly herbivorous marine animals and, in some cases, the algae on which they feed were determined by HPLC-ICP MS. In most cases arsenobetaine was present in the animals as well as arsenosugars consumed directly from the algae. However in the case of copepods Gladioferens imparipes fed only on the diatom Chaetoceros concavicornis which had been grown in axenic culture, arseno-betaine was absent. Arsenobetaine was also absent from the muscle of the silver drummer Kyphosus sydneyanus, although trimethyl-arsine oxide was present. This is the first reported case of the absence of arsenobetaine in a marine teleost fish and may be related to its fermentative faculty for digesting the macroalgae that it consumes. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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