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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 13 (1996), S. 327-332 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes the evaluation of the transfer function for the TSI-short differential mobility analyzer (DMA) in the nanometer particle size rang. The TSI-short DMA is identical with the TSI-long DMA (Model 3071) but has shortened inner and outer electrodes and the insulator material Teflon was replaced by black Delin. The DMA transfer function was determined by operating two identical DMAs in series. The DMA was investigated at a sheath to aerosol flow rate ratio of between 10 and 1. Usually for particles above 50 nm the parameters of the assumed triangular transfer function, i.e. height and half-width, approach the ideal values, which depend only on the flow ratio. For particle size below 50 nm the height decreases from 0.9 at 50 nm to 0.18 at 5 nm. The half-width increase from the ideal value 0.1 to about 0.17. The observed changes of the transfer function are due to diffusional effects resulting in losses mainly in the inlet and outlet and also broadening of the aerosol stream inside the DMA. The determined transfer functions were also compared with transfer functions calculated using a theoretical model. The agreement proved to be satisfactory. The half-widths and the transmission efficiencies of the conventional TSI-DMA (Model 3071), TSI-short with Teflon and also black Delin insulator as a function of particle size are compared to demonstrate the improvements in performance.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 7 (1990), S. 250-255 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The bipolar diffusion charging process is studied theoretically for aerosol particles in high purity argon and nitrogen. The Fuchs theory is extended by the incorporation of the free electron charging of the aerosol particles. The ion parameters for positive and negative ions are assumed to be identical. The influence of the free electrons explains the differences between the mean mobility and mean mass of negative and positive ions. The ratio of the electron number concentration to the number concentration of negative ions is used to fit the curves, calculated by the extended model, to the experimentally determined bipolar charge distribution in argon and nitrogen. The extended Fuchs model was found to be rather insensitive to variations in the mobility and mass compared with the model with four different ion parameters. Further experimental studies of the bipolar charge distribution in a gas mixture of pure nitrogen and sulfur hexafluoride, SF6, indicate the importance of the free electrons in the bipolar diffusion charging process.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 10 (1993), S. 33-37 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A scattered light photometer which monitors the particle number concentration of aerosols is described. The photometer measures the scattered light from illuminated submicron particle clouds with known material properties at certain scattering angles. Intensity ratios in combination with the degree of polarization are used to determine the mean particle diameter and the geometric standard deviation of an assumed log-normal particle size distribution. The determination of the particle size distribution is based on an algorithm which compares the measured and calculated (Mie theory) relative intensity quantities described. Furthermore, the particle number concentration is monitored from a single absolute intensity measurement at one scattering angle. In order to obtain quantitative results a spherical particle shape is required.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 13 (1996), S. 34-40 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microcontamination of product surfaces by deposited particles is an important problem in clean technologies. A most sensitive product to contamination by particles is a wafer during chip production. Therefore, methods for monitoring particle deposition on wafer surfaces have been developed in the last decade. A wafer with an unstructured and reflecting surface is inserted into the process equipment. After some time, depending on the process, this wafer is removed from the process equipment and is analysed with respect to the number of deposited particles using a wafer scanner. However, in situ particle detection in a process chamber is not possible with this technique. This would be possible if, instead of a monitor wafer, a transparent glass plate is mounted, e.g. in the housing of the process equipment. Then the illuminating and scattered light detection equipment can be mounted outside the process equipment. Since both the illuminating laser beam and the scattered light have to be transmitted through the glass plate, losses will occur, which will reduce the lower limit of detection with respect to particle size. In this article we estimate the detection possibilities theoretically and experimentally.A simple model based on Mie and vector scattering theory has been developed to describe the light-scattering behavior of a single spherical particle on a glass plate with random surface irregularities. The scattered light of individual particles of four particle sizes (1.03, 1.6, 2.92 and 4.23 μm) on the same glass surface and from the uncontaminated area of the glass plate was measured for unpolarized and normally incident light. The values of the scattered light from this model were compared with the experimental results. The comparison shows a reasonable agreement of the angular distribution of the scattered light. The developed model is used to predict the lower limit of detection for particles on a transparent surface. The theoretical estimations show that it should be possible to detect particles of a diameter down to 0.2 μm with the described measurement technique.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 2 (1985), S. 133-136 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: High capacity preseparators are used to reduce bounce and blow-off of large particles in cascade impactors. In this paper, results are presented of a detailed analysis of the deposition of particles in two slightly different preseparators of the impactor-type which are used in connection with the Andersen Stack Sampler. The advantage of using any preseparator for aerosols mixed with large particles (x 10 μm) is clearly shown.A preseparator which is integrated into the impactor has the advantages of smaller overall size, accessible surfaces and, therefore, easier handling. The results of the study show that the reduction of unwanted particle losses is rather small when compared with a separate preseparator.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 5 (1988), S. 165-169 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method based on the measurement of scattered light intensity distributions is demonstrated to be able to determine directly the particle size of monodisperse supermicron-size particles. In all other cases of a particle cloud, information about the size distribution can be acquired from comparison of measured and calculated intensities as a function of scattering angle. This indirect method is only applicable if the assumptions made in the theory used for comparison are fulfilled. Therefore, the method is limited to spherical particles with known refractive index. The type of size distribution also has to be known. In the cases considered a log-normal size distribution was assumed. The uncertainty of the result increases with increase in the number of parameters that have to be determined. The method seems to be limited to unimodal distributions described with two parameters.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 1 (1984), S. 108-111 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In optical particle counters the calibration function describing the relationship between the amplitude of the scattered light pulses and particle size depends on several parameters. In this paper, several calibration methods are discussed. As an example, the calibration of an optical particle counter (HC-15, Polytec GmbH & Co., Waldbronn, FRG) is demonstrated, using real aerosols with unknown particle shape and refractive index, and a precollector with known collection efficiency. The error analysis, when performed together with the results of an indirect check of the obtained calibration curve, provide evidence that this method yields good calibration curves for the aerosol being measured. The method is then applied to obtain the calibration curves for quartz dust, ash from a fluidized bed combustor and coal dust.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 3 (1986), S. 74-80 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particle penetrations through commercially available, electrically charged fibrous filters have been measured. The particles were monodisperse and in charge equilibrium. Tests were conducted for several particle sizes in the range 0.02 μm ≤ x ≤ 1 μm. The face velocity was varied in the range of 2 cm/s to 30 cm/s. The penetration has a bimodal dependence on particle size. This behaviour is not found for uncharged filters. The reduction in penetration and bimodal dependence is attributed to electrical collection effects. As the face velocity is increased, the electrostatic collection effects are significantly reduced. The results agree quantitatively with a model for particle penetration through charged fibrous filters recently presented in the literature by the authors.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 11 (1994), S. 359-366 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A log-normal model, based on the extended SIMPLER-algorithm utilizing the Modal Aerosol Dynamics Modelling Technique, and a sectional model are compared for Brownian coagulation in the transition regime. The models are in good agreement with respect to the calculated particle size distribution moments. Applying the log-normal model a simple coagulation model consisting of a closed set of five equations is developed that does not require the solution of ordinary diferential equations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 8 (1996), S. 559-560 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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