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  • Chemistry  (2)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 2637-2645 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Novel acrylic/methacrylic interpenetrating polymer networks (IPNs) were examined by dynamic mechanical spectroscopy for their damping capabilities. While simple homopolymers exhibit high damping properties only over a 20-30°C range, multicomponent polymer systems with controlled degree of miscibility, such as IPNs, may exhibit high damping properties over temperature ranges as broad as approximately 100°C. Two series of IPNs based on poly(n-butyl acrylate) and poly(n-butyl methacrylate) were synthesized and the dynamic mechanical properties were investigated using a Rheovibron. Graphite was incorporated into the poly(n-butyl acrylate) homopolymer and a few IPNs to measure the change in the damping properties. For important IPN compositions, tan δ values between 0.4 and 0.85 were observed over a 75°C plus temperature range. Graphite increased the damping properties of poly(n-butyl acrylate) and the IPNs, as indicated by the tan δ values.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The extent of molecular demixing of poly[cross-(ethyl acrylate)]-inter-poly[cross-(methyl methacrylate)] interpenetrating polymer networks (PEA/PMMA IPNs), of mid-range composition was investigated by decrosslinking and/or annealing using dynamic mechanical spectroscopy. A single broad transition characteristic of extensive but incomplete molecular mixing was observed for the PEA/PMMA IPN. The presence of crosslinking in both phases of an IPN enhances the mutual miscibility of the polymers. Through the use of a labile crosslinker, acrylic acid anhydride (AAA), polymer networks may be decross-linked, allowing the chains to separate and form two distinct phases. Annealing further sharpens the transitions, and phase separation becomes most pronounced when decrosslinking is followed by annealing.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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