ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A study of the CIDNP effects on methyl protons was carried out for the cage recombination products formed during the thermal decomposition reactions of peracetyls and peracetylcarbonates. The increase of both the cage recombination product yield and the enhancement of CIDNP on the CH3 protons is shown to be connected with the RCO2 radical lifetime, where R is an alkyl or alkoxy radical. A general theory of CIDNP is presented and the calculated data prove to be in satisfactory agreement with the experimental results.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270051109
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