ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The major electron impact induced fragmentation of 2-hydroxyphosphonic esters, XCH2CH(OH)CH2PO3Et2 (and their O-derivatives) involves the C(2)-C(3) α-cleavage, yielding the XCH2· radical and the oxocarbonium ion, +HO = CHCH2PO3Et2. No evidence for a competitive C(1)-C(2) α-cleavage was obtained, and the results suggest a stabilizing effect of the phosphonyl group on the α-oxocarbonium system.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210270112
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