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  • Chemistry  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    Termolecular reactions of alkali metal atoms with O2 and OH (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1567-1574 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Calculations of low-pressure limit, third-order rate constants are presented for the association reactions A + O2 + N2 and A + OH + N2 (A = Li, Na, K) over the temperature range 200-2000 K and a comparison is made with the available experimental data.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550161210
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Third-order rate constants of atmospheric importance (1983)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 15 (1983), S. 1189-1227 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Input data and results are presented for the calculation of a number of third-order rate constants of atmospheric interest using Troe′s approximate method. A comparison with experimental data indicates that this approach provides a reliable method for predicting unknown rate constants and estimating temperature dependences. These calculations form the basis of the recommendations of the NASA review panel for third-order rate constants to be used in atmospheric modeling.
    Additional Material: 27 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550151107
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Pyrolysis studies of main group metal-alkyl bond dissociation energies: VLPP of GeMe4, SbEt3, PbEt4, and PEt3 (1983)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 15 (1983), S. 167-185 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The bond dissociation energies of tetramethyl germane, triethyl stibine, tetraethyl lead, and triethylphosphine were determined using the technique of very-low-pressure pyrolysis. Arguments are presented for log A ≥ 17.0. The respective dissociation energies ΔH298 are 83, 57, 54, and 68 (±2) kcal/mol. A consistent set of methyl bond energies to main group metals is determined from these and previous results, and is examined for trends. Bond energies for various radicals to tin are also derived.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550150207
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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