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Construction of Quaternary Stereocenters by Nickel-Catalysis of Asymmetric Michael Reactions (2000)

Christoffers, Jens ; Rößler, Ulrich ; Werner, Thomas

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 701-705

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Details

ISSN: 1434-193X

Keywords: Asymmetric catalysis ; Catalysis ; Addition reactions ; N ligands ; Nickel ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---Quaternary stereocenters were constructed with an enantioselectivity of up to 91% ee under aerobic conditions and at ambient temperature in the Michael reaction of β-dicarbonyl compounds and methyl vinyl ketone with Ni(OAc)2·4H2O and optically active trans-1,2-diaminocyclohexane as a chiral catalyst.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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