ISSN:
0044-2313
Keywords:
Sodium copper scandium fluoride
;
sodium zinc aluminium fluoride
;
weberite structure
;
crystal structure determination
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The Crystal Structures of the Weberites Na2CuScF7 and Na2ZnAlF7At single crystals of the orthorhombic weberites Na2CuScF7 (Pmnb, Z = 4) and Na2ZnAlF7 (Imma, Z = 4) X-ray structure determinations were performed. Na2CuScF7 (Na2ZnAlF7): a = 726.0 (709.2), b = 1053.4 (1009.2), c = 765.8 (733.7) pm; R1 = 0.030 (0.042) for 887 (363) observed and independent reflections. The resulting average distances of the octahedrally coordinated metal atoms are: Cu—F = 200.7 pm, Sc—F = 201.7 pm; Zn—F = 198.8 pm, Al—F = 180.1 pm. Some structural relations and the variation in the bridge angles of the corner-sharing octahedra are discussed.
Notes:
An Einkristallen der orthorhombischen Weberite Na2CuScF7 (Pmnb, Z = 4) und Na2ZnAlF7 (Imma, Z = 4) wurden röntgenographische Strukturbestimmungen durchgeführt. Na2CuScF7 (Na2ZnAlF7): a = 726,0 (709,2), b = 1053,4 (1009,2), c = 765,8 (733,7) pm; R1 = 0,030 (0,042) für 887 (363) beobachtete und unabhängige Reflexe. Die resultierenden mittleren Abstände für die oktaedrisch koordinierten Metallatome sind: Cu—F = 200,7 pm, Sc—F = 201,7 pm; Zn—F = 198,8 pm, Al—F = 180,1 pm. Die Stukturverhältnisse und die Unterschiede in den Brückenwinkeln der eckenverknüpften Oktaeder werden diskutiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19946201005
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