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Chromium(VI)-Catalyzed Oxidations by Hydrogen Peroxide: Influence of the Presence of Water and Base (1998)

Bouquillon, Sandrine ; Aït-Mohand, Samia ; Muzart, Jacques

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 2599-2602

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Details

ISSN: 1434-193X

Schlagwort(e): Alcohols ; Chromium ; Oxidations ; Sodium percarbonate ; Peroxides ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The chromium(VI)-catalyzed oxidation of 1-indanol into 1-indanone has been carried out with sodium percarbonate (SPC), urea-hydrogen peroxide adduct (UHP), or aqueous hydrogen peroxide. It has been established that the superiority of SPC over UHP and aqueous H2O2 is due both to its nonhydrated structure and its basic properties. This classifies SPC as a “dry basic carrier of H2O2”.

Zusätzliches Material: 1 Tab.

Materialart: Digitale Medien

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