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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 50 (1988), S. 689-714 
    ISSN: 1572-9613
    Keywords: Classical lattice system ; variational principle ; cluster variation method ; tiling problem ; undecidability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In cluster approximations for lattice systems the thermodynamic behavior of the infinite system is inferred from that of a relatively small, finite subsystem (cluster), approximations being made for the influence of the surrounding system. In this context we study, for translation-invariant classical lattice systems, the conditions under which a state for a cluster admits an extension to a global translation-invariant state. This extension problem is related to undecidable tiling problems. The implication is that restrictions of global translation-invariant states cannot be characterized purely locally in general. This means that there is an unavoidable element of uncertainty in the application of a cluster approximation.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 7 (1986), S. 407-419 
    ISSN: 1572-9567
    Keywords: equation-of-state calculations ; polydisperse fluid ; vapor/liquid equilibrium ; variational approximation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A method is presented for approximate vapor/liquid equilibrium calculations using an equation of state. The method reduces the number of variables in the free-energy minimization problem by the introduction of suitably chosen additional constraints. It is based on a representation of a multicomponent fluid as a mixture of a small number of weakly polydisperse components. The approximation method can be used to accelerate sequences of vapor/liquid equilibrium calculations, such as are encountered in many engineering applications [plant design, hydrocarbon (oil/gas) reservoir simulation]. In realistic cases computing time has been reduced by up to 65%.
    Type of Medium: Electronic Resource
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