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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Space science reviews 90 (1999), S. 19-32 
    ISSN: 1572-9672
    Keywords: comet ; composition ; ice ; molecule ; spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The volatile species released in the coma are an important clue to the composition of the cometary nucleus ices. Their identification and the measurement of their abundances is possible by remote sensing. Considerable progress has been made recently using radio and infrared spectroscopy, especially with the observations of the two exceptional comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp).) 24 molecules likely to be parent molecules outgassed from the nucleus have now been identified. Significant upper limits exist for many other species, and the presence of unidentified lines suggests that further species are to be identified. In addition, isotopic varieties have been observed for hydrogen, carbon, nitrogen and sulphur. We will review these results with a special emphasis on the reliability of the identifications and of the molecular production rate determinations. A critical point is to assess whether a given species is a genuine parent molecule outgassed from nuclear ices, or is a secondary product coming from grains or from gas-phase photochemistry. Ground-based spectral imaging, such as radio interferometry, may help resolving this problem.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0794
    Keywords: Comets ; composition ; radio observations ; spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We present millimeter-wave observations of HNCO, HC3N, SO, NH2CHO, H13CN, and H3O+ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H2O is (4-13) × 10-4. HC3N, SO, and NH2CHO are detected for the first time in a comet. The fractional abundance of HC3N based on observations of three rotational lines is (1.9 ± 0.2) × 10-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH2CHO imply a fractional abundance of (1-8) × 10-4. H3O is detected for the first time from the ground. The H13CN (3-2)transition is also detected and the derived HCN/H13CN abundance ratio is 90 ± 15, consistent with the terrestrial12C/13C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO+, CO+, and CN(the last two are first detections in a comet at radio wavelengths).
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-0794
    Keywords: Comets ; C/1995 O1 (Hale-Bopp) ; radio observations ; molecules
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH3OH, H2CO,H2S, CS, CH3CN,HNC) have been monitored as a function of heliocentric distance(rh from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H2CO and CS showed a much steeper increase of the production rate with decreasing rh. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close torh 3.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-0794
    Keywords: Comets ; OH radical ; radio astronomy ; C/1995 O1 (Hale-Bopp)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We present OH 18-cm observations of comet Hale-Bopp (C/1995 O1) at the Nançay radio telescope. On nucleus and offset position observations allowed us to obtain both OH production rates and quenching radii. The maximum OH production rate was reached around perihelion, at about1031 s-1.
    Type of Medium: Electronic Resource
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