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Origin and information content of the compensation effect (1988)

Kreuzer, H. J. ; March, N. H.

Springer

Theoretical chemistry accounts 74 (1988), S. 339-348

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ISSN: 1432-2234

Keywords: Desorption ; Compensation ; Phase transitions

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract An attempt is made to assess: (i) The conditions under which a compensation effect should be observable, (ii) The associated physical properties affected by such compensation. (iii) The nature of the information which can be gleaned from studies of compensation. Specific attention is given to simple desorption processes and the main conclusion is that the compensation law in adsorption indicates a phenomenon involving many molecules. However the Meyer-Neldel rule in semiconductors is also embraced, as well as observations of the compensation effect in liquids.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00530231

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