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Theoretical interpretation of the anomalous behavior of some macromolecules (1988)

Paul, R. ; Fritz, O. G. ; Chatterjee, R.

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 34 (1988), S. 191-199

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Details

ISSN: 0020-7608

Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Recently, one of the members of this group (Fritz) has observed some unusual properties of rouleaugenic polymer solutions. It was found that the diffusion coefficient of polystyrene spheres in these solutions displayed an expected fall followed by an unexpected rise in values when the radii of these particles are changed. In this paper we present some of these experiments and provide a thermodynamic interpretation of the rise in the values of the diffusion coefficient.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/qua.560340717

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