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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of polyaniline/polytoluidine block copolymer via the pernigraniline oxidation state (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 35 (1994), S. 89-93 
    Details
    ISSN: 0959-8103
    Keywords: polyaniline ; pernigraniline oxidation state ; copolymer ; synthesis ; electrochemistry ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyaniline was electrochemically synthesized in the emeraldine oxidation state and then converted to the pernigraniline oxidation state by applying an electric potential under optimized conditions. The stability/reactivity of polyaniline in the pernigraniline oxidation state was evaluated in various aqueous media. The products of the reduction of the pernigraniline oxidation state by o-toluidine were analyzed by gel permeation chromatography, ultraviolet-visible and infrared spectroscopies, and cyclic voltammetry. The results are consistent with the synthesis of a diblock copolymer of polyaniline/poly(o-toluidine) and also of some poly(o-toluidine) homopolymer in the emeraldine oxidation state as a side product.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pi.1994.210350110
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  • 2
    Electronic Resource
    Electronic Resource
    Control of the Electronic Structure of Organic Conductors as Exemplified by [NMP][TCNQ] Charge-Transfer Complexes (1987)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 26 (1987), S. 287-293 
    Details
    ISSN: 0570-0833
    Keywords: Charge transfer ; Conducting materials ; Electron transport ; Materials science ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Through replacement of cations with neutral molecules of similar shape and polarizability in a highly conducting “metal-like” change-transfer organic conductor, the deliberate control of the electronic structure from a quarter to a half-filled band is possible. This goal has been achieved with the N-methylphenazinium (NMP) salt of the tetracyanoquinodimethane (TCNQ) anion by partial replacement of the cation with phenazine. A detailed study of the optical, electrical, and magnetic properties of these conducting molecular solids has lead to the evolution of a broad understanding of the physics of one-dimensional organic conductors and a reinterpretation of the mechanism of electron transport in such solids. Phenomena such as switching from a low coulomb repulsion two-chain conductor to a high coulomb repulsion one-chain conductor as well as soliton-assisted electron transport are observed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198702871
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    Paper (German National Licenses)
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