ISSN:
0948-5023
Keywords:
Keywords Nitrene additions, Buckminsterfullerene, C60, NCOOCH3, AM1, B3LYP/6-31G**//AM1
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Semiempirical and density functional calculations have been carried out to discuss the origin of the closed [5,6]-aza-bridged adduct obtained as a minor product in the reaction of singlet nitrenes with C60. The results indicated that the most likely source is the direct addition of singlet nitrenes to a [5,6]-bond of C60, in contradiction to the common belief that the [5,6]-bonds are not attacked in cycloaddition reactions to C60.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/s0089400060205
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