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  • 1
    ISSN: 1572-8935
    Keywords: IPNs ; Polyurethane ; Crosslinking density ; Phase separation ; Blood compatibility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Interpenetrating polymer networks (IPNs) of 2-hydroxyethyl methacrylate-terminated polyurethane (HPU) and polyurethane (PU) with different crosslinking densities of the PU network were prepared by simultaneous solution polymerization. Dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) show that compatibility of component polymers in IPN formation depends on the crosslinking density of the PU network. Physical properties such as density and water absorption rely on the subtle balance between the degree of phase separation and the crosslinking density of the PU network. In spite of the occurrence of phase separation, the tensile moduli and tensile strength of the IPNs increase with the crosslinking density of the PU network. Morphological observation by scanning electron microscopy revealed different fracture surfaces between the compatible and incompatible IPNs. Surface characteristics of the IPNs, indicated as hydrogen bonding index and hard-to-soft segment ratio, are altered considerably by varying surface morphologies. Improved blood compatibility of IPN membranes is due to the variation of the hydrophilic and hydrophobic domain distribution.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 40 (1996), S. 155-167 
    ISSN: 0959-8103
    Keywords: rhamsan gums ; xanthan gum ; rheology ; coal-water mixtures ; timber preservative emulsions ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The rheological properties of solutions of xanthan gum (Kelzan® D) and three rhamsan gums, S-60, S-130 and S-194, are examined. Effects studied include those of temperature, concentration and (for the rhamsan gums) extent of side chain branching. Solutions of greater viscosity and elasticity at most shear rates result as the degree of branching increases. When compared with xanthan gum, S-194 is found to be less temperature sensitive and more stable to excess shear. The use of these polymers in two commercial applications, i.e. coal-water mixtures and timber preservative emulsions, is also examined. Several advantages are identified when rhamsan gums are used instead of xanthan gum in both cases.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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