ISSN:
1572-879X
Keywords:
Zeolites
;
H-ZSM5
;
Cu-ZSM5
;
NO
;
Nitrosyl complexes
;
NO decomposition
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract In this note an exchange procedure of the acidic protons of H-ZSM5 by CuI ions through reaction with CuCl in the gas phase is described. In the so obtained CuI-ZSM5 exchanged zeolite the CuI ions are in well defined configuration and form with NO mono and di-nitrosyl complexes of high structural and spectroscopic quality. The CuI(NO)2 species are transformed at RT into CuII(NO)X (X=O− and/or NO 2 − ) species which could represent an intermediate in NO decomposition.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00770945
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